Statistical Indicators for Evaluating the Effect of Heavy Metals on Samaraa Drug Industry Water Exposed to the Sun and Freezing
http://www.doi.org/10.26538/tjnpr/v6i12.12
Keywords:
Pollution, Effluent, Wastewater, Multiple linear regression, Heavy metals, FreezingAbstract
Heavy metal poisoning is a worldwide problem caused by various human industrial activities such as battery and paint manufacturing, as well as occupational exposure of individuals working at petrol stations. Contaminated water and wastewater contain higher amounts of heavy metals such as chromium (Cr), aluminum (Al), copper (Cu), manganese (Mn), zinc (Zn), and iron (Fe), which may pose a risk to wastewater treatment plant workers. However, only a few studies have been conducted to assess the level of heavy metals and their subsequent effects. This study was therefore conducted to measure Samaraa pharmaceutical factory (SPF) work efficiency and predict the most important characteristics that affect water quality using the multiple linear regression (MLR) model. The case study location was the Samaraa Drug Industry, situated in Iraq. Water samples exposed to the sun and freezing were collected Pre and post factory operation. The concentrations (mg/L) of heavy metals (Cr, Al, Cu, Mn, Zn, and Fe) in the water samples were measured. Also, the influent, effluent, and samples exposed to sun and freezing were analyzed according to Iraqi standards for drinking water (ISL). The results show that the heavy metal data were normally distributed because the p-value was equal to 0.05 and the concentrations of substances in the river water were within the ISL acceptable limits. Meanwhile, Fe exceeded the ISL during the study period, but excellent results were obtained when the samples were exposed to the sun and freezing. Based on the coefficient of correlation, the MLR model (R2 of 91.4 %) proved efficient.
References
Abbas MN and Abbas FS. Iraqi Rice Husk Potency to Eliminate Toxic Metals from Aqueous Solutions and Utilization from Process Residues. Adv Environ Biol. 2013; 7(2):308-319.
Ibrahim SA, Hasan MB, Al-Tameemi IM, Ibrahim TA, Abbas MN. Optimization of adsorption unit parameter of hardness remediation from wastewater using low-cost media. Innov Infrastruct Solut. 2021; 6(4):1-12.
Ibrahim TA, Mahdi HS, Abbas RS, Abbas MN. Study the Effect of Ribavirin Drug on the histological structure of the testes in Albino mice (Mus musculus).2020; 12(02 Suppl.):142-146.
Chowdhury R, Ramond A, O’Keeffe, LM, Shahzad S, Kunutsor SK, Muka T, Gregson J, Willeit P, Warnakula S, Khan H, Chowdhury S, Gobin R, Franco OH, Di Angelantonio E. Environmental toxic metal contaminants and risk of cardiovascular disease: systematic review and metaanalysis. BMJ. 2018; 362: doi: https://doi.org/10.1136/bmj.k3310
Abbas MN, Al-Madhhachi AT, Esmael SA. Quantifying soil erodibility parameters due to wastewater chemicals. Int J Hydrol Sci Technol. 2019; 9(5):550-568.
Al Mashhadani AM. A Rapid Graphical Solution for Determining the Presence of Remnant Magnetization in the Basement Rocks of Western Iraq. INJES. 2008; 8(2):1-10.
Abbas MN and Abbas FS. The Predisposition of Iraqi Rice Husk to Remove Heavy Metals from Aqueous Solutions and Capitalized from Waste Residue. J Appl Sci Eng Technol. 2013; 6(22):4237-4246.
Abbas MN and Abbas FS. The Feasibility of Rice Husk to Remove Minerals from Water by Adsorption and Avail from Wastes. WSEAS Trans Environ Dev. 2013; 9(4):301-313.
Ghulam NA, Abbas MN, Sachit DE. Preparation of synthetic alumina from aluminium foil waste and investigation of its performance in the removal of RG-19 dye from its aqueous solution. Indian Chem Eng. 2020; 62(3):301-313.
Alalwan HA, Abbas MN, Alminshid AH. Uptake of Cyanide Compounds from Aqueous Solutions by Lemon Peel with Utilising the Residue Absorbents as Rodenticide. Indian Chem. Eng. 2020; 62(1):40-51.
Hassan FM, Salman JM, Al-Yassiry TMH. Ecological Observation on Phytoplankton Species Composition in Wastewater Treatment Plant / Iraq. IJAR. 2014; 2(8):344-356.
Abd AK, Ibrahim TA, Farhan AD, Abbas MN. Study of the effect of pesticide 2,4-D on the histological structure of the lungs in the albino mice (Mus musculus). J Pharm Sci Res. 2018; 10(6):1418-1421.
Alluhaiby AA, Saadat M, Shaima F. The Effect of Purification Units for Drinking Water Spread in Al-Alam and Al-Bu Ajil on Heavy Metals. IJRASB. 2021; 8(3):110–115.
Ibrahim TA, Mohammed AM, Abd AK, Abbas MN, Hussien SA. Teratogenic Effect of Carbamazepine Drug on the Histological Structure of Testes in the Albino Mouse (Mus musculus). Indian J Med Forensic Med Toxicol. 2020; 14(4):1829-1834.
Adebayo AH, Yakubu OF, Ezekiel-Hart ES, Okubena O. Antimicrobial and Toxicity Studies on Holisa Herbal Formulation. Trop J Nat Prod Res. 2021; 5(5):983-987.
Al-Hassen SI, Al-Rubaiay DJ, Al-Saad HT. Levels of Heavy Metals Pollution in the Aquatic Environment of Basra City, Iraq. 4th Conference of Environmental Sciences, University of Babylon. 5-6 December. 2012; 315-332.
Abdullah EJ. Quality Assessment for Shatt Al-Arab River Using Heavy Metal Pollution Index and Metal Index. Environ Earth Sci. 2013; 3(5):114-120.
Salal AM and Khudair BH. Influent Flow Rate Effect on Sewage Pump Station Performance Based on Organic and Sediment Loading. J Eng. 2019; 25(9):1–11.
Abbas MN, Ali ST, Abbas RS. Rice Husks as a Biosorbent Agent for Pb+2 Ions from Contaminated Aqueous Solutions: A Review. Biochem Cell Arch. 2020; 20(1):1813-1820.
Abbas MN and Abbas FS. Application of Rice Husk to Remove Humic Acid from Aqueous Solutions and Profiting from Waste Leftover. WSEAS Transactions on Biology and Biomedicine. 2014; 11(2014):62-69.
Maddodi SA, Alalwan HA, Alminshid AH, Abbas MN. Isotherm and computational fluid dynamics analysis of nickel ion adsorption from aqueous solution using activated carbon. S Afr J Chem Eng. 2020; 32:5-12.
Abbas MN. Phosphorus removal from wastewater using rice husk and subsequent utilization of the waste residue. Desalination and Water Treatment. 2015; 55(4):970-977.
Abbas MN, Al-Hermizy SMM, Abudi ZN, Ibrahim TA. Phenol Biosorption from Polluted Aqueous Solutions by Ulva lactuca Alga using Batch Mode Unit. J Ecol Eng. 2019; 20(6):225–235.
Alalwan HA, Abbas MN, Abudi ZN, Alminshid AH. Adsorption of thallium ion (Tl+3) from aqueous solutions by rice husk in a fixed-bed column: Experiment and prediction of breakthrough curves, Environ Technol Innov. 2018; 12:1-13.
Abbas MN and Nussrat TH. Statistical Analysis of Experimental Data for Adsorption Process of Cadmium by Watermelon Rinds in Continuous Packed Bed Column. Int J Innov. 2020; 13(13):124-138.
Ali SAK, Almhana NM, Hussein AA, Abbas MN. Purification of Aqueous Solutions from Toxic Metals using Laboratory BatchMode Adsorption Unit Antimony (V) Ions as a Case Study. JGE. 2020; 10(11):10662-10680.
Ali GAA and Abbas MN. Atomic Spectroscopy Technique Employed to Detect the Heavy Metals from Iraqi Waterbodies Using Natural Bio-Filter (Eichhornia crassipes) Thera Dejla as a Case Study. Syst Rev Pharm. 2020; 11(9):264-271.
Hasan MB, Al-Tameemi IM, Abbas MN. Orange Peels as a Sustainable Material for Treating Water Polluted with Antimony. J Ecol Eng. 2021; 22(2):25-35.
Alwan EK, Hammoudi AM, Abd IK, Abd Alaa MO, Abbas MN. Synthesis of Cobalt Iron Oxide Doped by Chromium Using SolGel Method and Application to Remove Malachite Green Dye. NeuroQuantology. 2021; 19(8):32-41.
Alminshid AH, Abbas MN, Alalwan HA, Sultan AJ, Kadhome MA. Aldol condensation reaction of acetone on MgO nanoparticles surface: An in-situ drift investigation. Mol Catal. 2021; 501:111333.
Abbas MN, Al-Tameemi IM, Hasan MB, Al-Madhhachi AT. Chemical Removal of Cobalt and Lithium in Contaminated Soils using Promoted White Eggshells with Different Catalysts. S Afr J Chem Eng. 2021; 35:23-32.
Ali GAA, Ibrahim SA, Abbas MN. Catalytic Adsorptive of Nickel Metal from Iraqi Crude Oil using non-ConventionalCatalysts. Innov Infrastruct Solut. 2021; 6:7.
Alalwan HA, Mohammed MM, Sultan AJ, Abbas MN, Ibrahim TA, Aljaafari HAS, Alminshid AH. Adsorption of methyl green stain from aqueous solutions using non-conventional adsorbent media: Isothermal kinetic and thermodynamic studies. Bioresour Technol. 2021; 14:100680.
Abbas MN, Alalwan HA. Catalytic Oxidative and Adsorptive Desulfurization of Heavy Naphtha Fraction”, Korean J Chem Eng. 2019; 12(2):283-288.
Abbas MN and Ibrahim SA. Catalytic and thermal desulfurization of light naphtha fraction. JKSUES. 2020; 32(4):229-235.
Abbas MN, Ibrahim SA, Abbas ZN, Ibrahim TA. Eggshells as a Sustainable Source for Acetone Production. JKSUES. 2021; 34(6):381-387
Saleh RF, Gaidan AM, Al-Mayah QS. Green Synthesis of Silver Nanoparticles using Aqueous Leaf Extract of Ocimum basilicum and Investigation of their Potential Antibacterial Activity. Trop J Nat Prod Res. 2021; 5(1):94-99.
Abbas FS, Abdulkareem WS, Abbas MN. Strength Development of Plain Concrete Slabs by the Sustainability Potential of LeadLoaded Rice Husk (LLRH). J Appl Eng Sci. 2022; 20(1):160-167.
Ali ST, Qadir HT, Moufak SK, Al-Badri MAM, Abbas MN. A Statistical Study to Determine the Factors of Vitamin D Deficiency in Men the City Of Baghdad as a Model. AMJ. 2020; 14(1):691-696.
Naji TS, Ali ST, Alwan IA, Abbas MN. Effect of Iron Deficient on the Pregnant Women. BNIHS. 2022; 140(01):845-853.
American Public Health Association. Standard Methods for the Examination of Water and Wastewater, 21st edition. Washington DC: APHA.2005. 42. Jamshaid M, Ali Khan A, Ahmed K, Saleem M. Heavy metal in drinking water its effect on human health and its treatment techniques - a review. IJB. 2018; 12(4):223-240.
AWWA. Manual of Water Supply Practices M1, Principles of Water Rates, Fees and Charges, 5th ed. AWWA, Denver. 2000.
Wogu MD and Okaka CE. Pollution Studies on Nigerian Rivers: Heavy Metals in Surface Water of Warri River, Delta State. JBES. 2011; 1:7-12.
Gautam RK, Sharma SK, Mahiya S, Chattopadhyaya MC. Heavy Metals in Water, Chapter 1. Contamination of Heavy Metals in Aquatic Media: Transport, Toxicity and Technologies for Remediation” from the book: Heavy Metals in Water: Presence, Removal and Safety. 2014:1–24.
American Public Health Association. Standard methods for the Examination of water and wastewater, 23rd edition. Washington DC: APHA. 2017.
Liu Y. Application of graphene oxide in water treatment. IOP Conference Series: Earth and Env Sci EEMS. 2017; 94.
Abedi AS, Nasseri E, Esfarjani F, Mohammadi-Nasrabadi F, Hashemi MM, Hoseini H. A systematic review and meta-analysis of lead and cadmium concentrations in cow milk in Iran and human health risk assessment. ESPR. 2020; 27(10):10147– 10159.
Mahmood A and Malik RN. Human health risk assessment of heavy metals via consumption of contaminated vegetables collected from different irrigation sources in Lahore, Pakistan. Arab J Chem. 2014; 7(1):91-99.
Onundi YB, Mamun AA, Al Khatib MF, Ahmed YM. Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon. IJEST. 2010; 7(4):751-758.
Al-Rawi SYB. Survey Study of some Heavy metals for the Euphrates River Basin in Al-Ramadi city. MSc. Thesis, College of Science, University of Anbar. 2019.
Ghawi AH. Study of the Reuse of Greywater in the Irrigation of the Home Garden in Rural Areas. J Appl Sci Eng. 2001; 12(6):7944-7950.
Altinay L, Madanoglu M, De Vita G, Arasli H, Ekinci Y. The Interface between Organizational Learning Capability, Entrepreneurial Orientation, and SME Growth. J. Small Bus. Manag. 2016; 54(3):871-891.
Konietschke F, Placzek M, Schaarschmidt F, Hothorn LA. nparcomp: an R software package for nonparametric multiple comparisons and simultaneous confidence intervals. J Stat Softw. 2015; 64(9):1-17.
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